Product ID:48059 EPA HC PURGEABLE A
MSDS Date:07/27/1993
FSC:6810
NIIN:00F037599
Kit Part:Y
MSDS Number: BWJLR

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 97.2%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON TETRACHLORIDE (SUSPECTED CARCINOGEN BY ACGIH,

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.2%

OSHA PEL 2 PPM

ACGIH TLV: 31 MG/CUM SKIN (A2)

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

CHLOROFORM (TRICHLOROMETHANE)(SUSPECTED HUMAN CARCINOGEN BY

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 0.2%

OSHA PEL 240 MG/CUM

ACGIH TLV: 50 MG/CUM (A2)

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.2%

OSHA PEL 500 PPM

ACGIH TLV: 174 MG/CUM (A2)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

FLUOROTRICHLOROMETHANE, FREON 11, TRICHLOROFLUOROMETHANE,

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 0.2%

OSHA PEL 1000 PPM

ACGIH TLV: 262 MG/CUM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CHLOROBENZENE (MONOCHLOROBENZENE) (CONFIRMED ANIMAL

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.2%

OSHA PEL 350 MG/CUM

ACGIH TLV: 46 MG/CUM IC

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,1-DICHLOROETHANE (ETHYLIDINE CHLORIDE)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.2%

OSHA PEL 400 MG/CUM

ACGIH TLV: 810 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,1,2-TRICHLOROETHANE (SUSPECTED ANIMAL CARCINOGEN BY IARC

CAS: 79-00-5

RTECS: KJ3150000

Fraction By Weight: 0.2%

OSHA PEL 45 MG/CUM

ACGIH TLV: 55 MG/CUM (SKIN)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

2-CHLOROETHYLVINYL ETHER

CAS: 110-75-8

RTECS: KN6300000

Fraction By Weight: 0.2%

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-DICHLOROBENZENE, 1,2-DICHLOROBENZENE (ORTHO)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: 0.2%

OSHA PEL 300 MG/CUM

ACGIH TLV: 301 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

VINYLIDENE CHLORIDE, 1,1-DICHLOROETHENE,

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.2%

OSHA PEL 1 PPM

ACGIH TLV: 20 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-DICHLOROROPANE

CAS: 78-87-5

RTECS: TX9625000

Fraction By Weight: 0.2%

OSHA PEL 75 PPM

ACGIH TLV: 347 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHLORODIBROMOMETHANE

CAS: 124-48-1

RTECS: PA6360000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SUSPECTED ANIMAL

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.2%

OSHA PEL 25 PPM

ACGIH TLV: 339 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TRICHLOROETHYLENE, TCE, TRICHLOROETHENE (IARC HUMAN

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.2%

OSHA PEL 50 PPM

ACGIH TLV: 269 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG METHANOL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. INGESTION: FATAL.
GASTROINTESTINAL DISTURBANCES. EYES: MAY CAUSE BLINDNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:HEADACHE, NAUSEA, GI DISTURBANCES.

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER. INHALATION: MOVE TO FRESH AIR. GIVE CPR IF NECESSARY.
INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. NEVER TRY
TO MAKE AN UNCON SCIOUS PERSON VOMIT. GIVE 2 TABLESPOONSOF BAKING
SODA IN A GLASS OF WATER & PRESS FINGERS TO BACK OF TONGUE TO
INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:50F
Lower Limits:6
Upper Limits:36
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN A
FREEZER. KEEP AWAY FROM OXIDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES.
Supplemental Safety and Health

Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER=1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANYDRIDE, LEAD PERCHLORATE, PERCHLORIC ACIDS
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN BROMIDE,
HYDROGEN FLUORIDE, PHOSGENE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.